You need to allow this for a user account:
- Admin center > Active users > select the user:
- Select Mail > Email apps > Manage email apps:
- here you need to turn on "Authenticated SMTP"

after you did that you can use this smtp server settings in your application:
- E-Mailserver: smtp.office365.com
- Port: 587
- Username: your Office 365 email address
- Psssword: your password
- ssl: turn on

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